Cd (II) removal from aqueous solution by Eleocharis acicularis biomass, equilibrium and kinetic studies.

Batch experiments were carried out to determine the capacity of Eleocharis acicularis biomass to adsorb Cd(2+) ions from contaminated solutions with respect to pH, initial Cd(2+) concentration, contact time, solution ionic strength and biomass dose. The experimental data were modeled by Langmuir, Freundlich and Dubinin-Radushkevich (D-R) isotherm models. Freundlich and D-R models resulted in the best fit of the adsorption data. The maximum adsorption capacity for Cd(2+) was 0.299 mmol g(-1) (33.71 mg g(-1)) with efficiency higher than 80% (pH 6.0 and 5 g L(-1) biomass dose). The mean adsorption free energy value derived from the D-R model (8.058 kJ mol(-1)) indicated that adsorption was governed by an ionic exchange process. The pseudo-first order, pseudo-second order, Elovich kinetic models and the intra-particle diffusion models were used to describe the kinetic data and to evaluate rate constants. The best correlation was provided by the second-order kinetic model, implying that chemical sorption was the rate-limiting step, although intra-particle diffusion could not be ignored. The practical implication of this study is the development of an effective and economic technology for Cd(2+) removal from contaminated waters. The macrophyte biomass used in this study did not undergo any chemical or physical pre-treatment, which added to macrophyte abundance and its low cost makes it a good option for Cd(2+) removal from waste water.

Experimental binding of lead to a low cost on biosorbent: Nopal (Opuntia streptacantha).

The use of nopal cladodes (Opuntia streptacantha) as raw material for Pb(2+) biosorption was investigated. Batch experiments were carried out to determine Pb(2+) sorption capacity and the efficiency of the sorption process under different pH, initial Pb(2+) and nopal biomass concentrations. The experimental data showed a good fit to Langmuir and Freundlich isotherms models. The maximum adsorption capacity for Pb(2+) was 0.14 mmol g(-1) with an efficiency higher than 94% (pH 5.0 and 2.5 g L(-1) nopal biomass). The Pb(2+) kinetics were best described by the pseudo-second-order rate model. The rate constant, the initial sorption rate and the equilibrium sorption capacity were determined. The practical implication of this study is the development of an effective and economic technology in which the nopal biomass did not undergo any chemical or physical pretreatment, which added to nopal abundance in Mexico and its low cost makes it a good option for Pb(2+) removal from contaminated waters.

Experimental Zn(II) retention in a sandy loam soil by very small columns.

The use of column experiments, usually performed to better approximate field conditions, may provide information that is not available from batch experiments. In such experiments heavy metals are often adsorbed until saturation followed by desorption experiments. When the affinity of the metal to soil is high, the retention factor (R) could be greater than thousands and the duration of experiments can become impractically long. In order to use reasonable laboratory time, the flow rate should be increased or the column size decreased. The increase in flow rate produces undesirable kinetic and dispersion effects, so we used very small soil columns (pore volume=0.31-0.70 ml) and relatively high flow rates (0.03-0.12 ml min(-1)) in studies of Zn(II) adsorption and retention in soils. Conservative tracer flow column experiments under saturation conditions were carried out to determine flow parameters for different flow rates. Column pore volume (V(p)), Peclet numbers (Pe) and longitudinal dispersion coefficients (D(L)) were determined from breakthrough curves. The effect of type of electrolyte and ionic strength on the Zn(II) retention onto soil was determined. The influence of flow rate and bed height on the retention coefficient and on the mass transfer zone was also studied. The effect of different influent Zn(II) concentrations on the R values obtained was analyzed. Freundlich parameters from column experiments were compared with batch ones. The leaching efficiency of different electrolytes, salts of weak organic acids and EDTA was also studied.

Simultaneous heavy metal removal mechanism by dead macrophytes.

The use of dead, dried aquatic plants, for water removal of metals derived from industrial activities as a simple biosorbent material has been increasing in the last years. The mechanism of simultaneous metal removal (Cd2+, Ni2+, Cu2+, Zn2+ and Pb2+) by 3 macrophytes biomass (Spirodela intermedia, Lemna minor and Pistia stratiotes) was investigated. L. minor biomass presented the highest mean removal percentage and P. stratiotes the lowest for all metals tested. Pb2+ and Cd2+ were more efficiently removed by the three of them. The simultaneous metal sorption data were analysed according to Langmuir and Freundlich isotherms. Data fitted the Langmuir model only for Ni and Cd, but Freundlich isotherm for all metals tested, as it was expected. The K(F) values showed that Pb was the metal more efficiently removed from water solution. The adsorption process for the three species studied followed first order kinetics. The mechanism involved in biosorption resulted ion exchange between monovalent metals as counter ions present in the macrophytes biomass and heavy metal ions and protons taken up from water. No significant differences were observed in the metal exchange amounts while using multi-metal or individual metal solutions.

Sorption of mercury (II) in Amazon soils from column studies.

The sorption of Hg (II) onto four different types of Amazon soils from the A-horizon was investigated by means of column experiments under saturation conditions and controlled metal load. Higher organic matter contents in the soil resulted in higher Hg (II) adsorptions, reaching values as high as 3.8 mg Hg g(-1) soil. The amount of mercury adsorbed on a soil column (Q) shows a very poor correlation with soil clay content (r2 = 0.2527), indicating that Hg sorption in these topsoil samples is chiefly governed by the organic matter content. Desorption experiments using Negro River (Amazon) waters were conducted using soil saturated with Hg (II) in order to better understand the metal leaching mechanism. The amount of Hg (II) released from soils was around 30% of the total sorbed mercury upon saturation, suggesting that mercury sorption in the soils present in the catchment area of the Negro River basin is not a reversible process.

Aquatic macrophytes potential for the simultaneous removal of heavy metals (Buenos Aires, Argentina).

Heavy metal removal from water has been approached by using different technologies. Phytotechnologies, with an increasing development during the last two decades, involve using plants for metal removal. Three autochthonous floating macrophytes, common in pampean shallow lakes (Argentina), Pista stratiotes, Spirodela intermedia and Lemna minor were used in laboratory experiences for the simultaneously removal of several heavy metals (Fe, Cu, Zn, Mn, Cr and Pb) resulting from anthropogenic activity, in order to simulate a naturally polluted environment. The experiences were performed for different concentrations of metals along 15 days. High metal removal percentages were obtained for the 3 species and metals. L. minor did not survive the conditions of the experiment. High correlation between the final water and the macrophytes metal concentration was obtained, deviations were due to PbCrO(4) precipitation. The rate of metal uptake was dependent on the metal concentration for the 3 species studied.